1 verse has
ٱلزَّوْجَيْنِ
in Edition Uthmani / An-Najm (The Star)

45:53وَأَنَّهُۥ خَلَقَ ٱلزَّوْجَيْنِ ٱلذَّكَرَ وَٱلْأُنثَىٰ