2 verses have
“appoint”
in Edition Clear Qur'an by Talal Itani / An-Nisaa (The Women)
4:35If you fear a breach between the two, appoint an arbiter from his family and an arbiter from her family. If they wish to reconcile, God will bring them together. God is Knowledgeable, Expert.
4:75And why would you not fight in the cause of God, and the helpless men, and women, and children, cry out, “Our Lord, deliver us from this town whose people are oppressive, and appoint for us from Your Presence a Protector, and appoint for us from Your Presence a Victor.”
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Those who spend their wealth by night and day, privately and publicly, will receive their reward from their Lord. They have nothing to fear, nor shall they grieve.
The Holy Quran · Al-Baqara (The Cow) · 2:274