2 verses have
“pain”
in Edition Clear Qur'an by Talal Itani / Al-Jaathiya (Crouching)
45:8Who hears God's revelations being recited to him, yet he persists arrogantly, as though he did not hear them. Announce to him a painful punishment.
45:11This is guidance. Those who blaspheme their Lord’s revelations will have a punishment of agonizing pain.
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Those who spend their wealth by night and day, privately and publicly, will receive their reward from their Lord. They have nothing to fear, nor shall they grieve.
The Holy Quran · Al-Baqara (The Cow) · 2:274