1 verse has
“douloureux”
in Edition Muhammad Hamidullah / As-Saaffaat (Those drawn up in Ranks)
37:38Vous allez certes, goûter au châtiment douloureux.
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Those who spend their wealth by night and day, privately and publicly, will receive their reward from their Lord. They have nothing to fear, nor shall they grieve.
The Holy Quran · Al-Baqara (The Cow) · 2:274